By Robert H. Grubbs, Anna G. Wenzel
There's most likely no identify extra heavily associated with metathesis than that of Robert H. Grubbs of the California Institute of expertise. His pioneering paintings has ended in the luck of this crucial and interesting response and during this accomplished three-volume paintings he provides all its very important aspects.
- The average paintings at the subject
- The workforce of authors reads like a "Who's who" of metathesis
- Clearly divided into catalyst advancements, natural synthesis purposes and polymer synthesis
- A must-have for each natural and polymer chemist
Chapter 1.1 advent (pages 1–3): Robert H. Grubbs
Chapter 1.2 The function of the “Tebbe advanced” in Olefin Metathesis (pages 4–7): Robert H. Grubbs
Chapter 1.3 the invention and improvement of excessive Oxidation country Mo and W Imido Alkylidene Complexes for Alkene Metathesis (pages 8–32): Richard R. Schrock
Chapter 1.4 From Ill?Defined to Well?Defined W Alkylidene Complexes (pages 33–46): Christophe Coperet, Frederic Lefebvre, Jean?Marie Basset and M. Leconte
Chapter 1.5 Fischer steel Carbenes and Olefin Metathesis (pages 47–60): Thomas J. Katz
Chapter 1.6 the invention and improvement of Well?Defined, Ruthenium?Based Olefin Metathesis Catalysts (pages 61–85): SonBinh T. Nguyen and Tina M. Trnka
Chapter 1.7 Synthesis of Ruthenium Carbene Complexes (pages 86–94): Warren R. Roper
Chapter 1.8 Synthesis of Rhodium and Ruthenium Carbene Complexes with a 16?Electron count number (pages 95–111): Helmut Werner and Justin Wolf
Chapter 1.9 Mechanism of Ruthenium?Catalyzed Olefin Metathesis Reactions (pages 112–131): Melanie S. Sanford and Jennifer A. Love
Chapter 1.10 Intrinsic Reactivity of Ruthenium Carbenes (pages 132–172): Christian Adlhart and Peter Chen
Chapter 1.11 the invention and improvement of excessive Oxidation country Alkylidyne Complexes for Alkyne Metathesis (pages 173–189): Richard R. Schrock
Chapter 1.12 Well?Defined Metallocarbenes and Metallocarbynes Supported on Oxide helps ready through floor Organometallic Chemistry: A resource of hugely energetic Alkane, Alkene, and Alkyne Metathesis Catalysts (pages 190–204): Christophe Coperet, Frederic Lefebvre and Jean?Marie Basset
Chapter 2.1 Olefin Metathesis and comparable Reactions in natural Synthesis: advent to Metal?Carbon Double Bonds in natural Synthesis (pages 1–4): Robert H. Grubbs
Chapter 2.2 normal Ring?Closing Metathesis (pages 5–127): So?Yeop Han and Sukbok Chang
Chapter 2.3 Catalytic uneven Olefin Metathesis (pages 128–150): Amir H. Hoveyda
Chapter 2.4 Tandem Ring?Closing Metathesis (pages 151–175): Stefan Randl and Siegfried Blechert
Chapter 2.5 Ene?Yne Metathesis (pages 176–204): Miwako Mori
Chapter 2.6 Ring?Opening Cross?Metatheses (pages 205–237): Thomas O. Schrader and Marc L. Snapper
Chapter 2.7 Ring?Expansion Metathesis Reactions (pages 238–245): Choon Woo Lee
Chapter 2.8 Olefin Cross?Metathesis (pages 246–295): Arnab ok. Chatterjee
Chapter 2.9 Olefin Metathesis concepts within the Synthesis of Biologically suitable Molecules (pages 296–322): Jennifer A. Love
Chapter 2.9 Vignette 1: The Olefin Metathesis response in advanced Molecule building (pages 323–337): okay. C. Nicolaou and Scott A. Snyder
Chapter 2.9 Vignette 2: purposes of Ring?Closing Metathesis to Alkaloid Synthesis (pages 338–352): Stephen F. Martin
Chapter 2.9 Vignette three: Radicicol and the Epothilones: overall Synthesis of Novel Anticancer brokers utilizing Ring?Closing Metathesis (pages 353–360): Jon T. Njardarson, Robert M. Garbaccio and Samuel J. Danishefsky
Chapter 2.10 using Olefin Metathesis in Combinatorial Chemistry: Supported and Chromatography?Free Syntheses (pages 361–402): Andrew M. Harned, Donald A. Probst and Paul R. Hanson
Chapter 2.11 Metal?Catalyzed Olefin Metathesis in steel Coordination Spheres (pages 403–431): Eike B. Bauer and J. A. Gladysz
Chapter 2.12 Alkyne Metathesis (pages 432–462): Alois Furstner
Chapter 2.13 Metathesis of Silicon?Containing Olefins (pages 463–490): Bogdan Marciniec and Cezary Pietraszuk
Chapter 2.14 advertisement purposes of Ruthenium Metathesis methods (pages 491–510): Richard L. Pederson
Chapter 3.1 creation (page 1): Robert H. Grubbs
Chapter 3.2 residing Ring?Opening Olefin Metathesis Polymerization (pages 2–71): Grainne Black, Declan Maher and Wilhelm Risse
Chapter 3.3 Synthesis of Copolymers (pages 72–117): Ezat Khosravi
Chapter 3.4 Conjugated Polymers (pages 118–142): W. James Feast
Chapter 3.5 Stereochemistry of Ring?Opening Metathesis Polymerization (pages 143–179): James G. Hamilton
Chapter 3.6 Syntheses and functions of Bioactive Polymers Generated by means of Ring?Opening Metathesis Polymerization (pages 180–225): Laura L. Kiessling and Robert M. Owen
Chapter 3.7 Metathesis Polymerization: a flexible software for the Synthesis of Surface?Functionalized helps and Monolithic fabrics (pages 226–254): Michael R. Buchmeiser
Chapter 3.8 Telechelic Polymers from Olefin Metathesis Methodologies (pages 255–282): Christopher W. Bielawski and Marc A. Hillmyer
Chapter 3.9 ADMET Polymerization (pages 283–353): Stephen E. Lehman and Kenneth B. Wagener
Chapter 3.10 Acyclic Diyne Metathesis using in Situ Transition steel Catalysts: a good entry to Alkyne?Bridged Polymers (pages 354–374): Uwe H. F. Bunz and ok. Peter C. Vollhardt
Chapter 3.11 Polymerization of Substituted Acetylenes (pages 375–406): Toshio Masuda and Fumio Sanda
Chapter 3.12 advertisement functions of Ruthenium Olefin Metathesis Catalysts in Polymer Synthesis (pages 407–418): Mark S. Trimmer
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Extra resources for Handbook of Metathesis: Catalyst Development
H. J. Am. Chem. Soc. 1986, 108, 733. Sharp, P. ; Schrock, R. R. J. Organometal. Chem. 1979, 171, 43. Wengrovius, J. ; Schrock, R. ; Churchill, M. ; Missert, J. ; Youngs, W. J. J. Am. Chem. Soc. 1980, 102, 4515. Churchill, M. ; Rheingold, A. ; Youngs, W. ; Schrock, R. R. J. Organometal. Chem. 1981, 204, C17. Wengrovius, J. ; Schrock, R. R. Organometallics 1982, 1, 148. Schaverien, C. ; Dewan, J. ; Schrock, R. R. J. Am. Chem. Soc. 1986, 108, 2771. Schrock, R. ; Schaverien, C. ; Dewan, J. ; Liu, A.
Grubbs, Organometallics 1989, 8, 583– 589. 8 E. V. Anslyn, R. H. Grubbs, J. Am. Chem. Soc. 1987, 109, 4880–4890. T. Ikariya, S. C. H. Ho, R. H. Grubbs, Organometallics 1985, 4, 199. J. M. Hawkins, R. H. Grubbs, J. Am. Chem. Soc. 1988, 110, 2821–2823. 9 J. Kress, J. A. Osborn, K. J. Ivin, J. J. Rooney, J. Am. Chem. Soc. 1987, 109, 899. 10 R. H. Grubbs, C. Hoppin, J. Am. Chem. Soc. 1979, 101, 1499 and references therein. 11 L. R. Gilliom, R. H. Grubbs, J. Am. Chem. Soc. 1986, 108, 733–742. 3 The Discovery and Development of High Oxidation State Mo and W Imido Alkylidene Complexes for Alkene Metathesis Richard R.
Closer to metal-carbon double-bond lengths than to typical acyclic metal-carbon single-bond lengths. 3-2). They are the most stable toward loss of oleﬁn for a variety of alkoxides. Methylene complexes of the type W(NAr)(CH2 )(OR)2 could not be observed and are believed to decompose bimolecularly via formation of a species that contains two bridging methylene ligands. 3 The Discovery and Development of High Oxidation State Mo and W Imido Alkylidene Complexes Fig. 3-4. 738(9) A˚. to rearrange readily to oleﬁns.
Handbook of Metathesis: Catalyst Development by Robert H. Grubbs, Anna G. Wenzel