By Yu-Ran Luo
SynopsisDrawn from over 5,500 assets, entire instruction manual of Chemical Bond Energies compiles the newest experimental BDE facts for greater than 19,600 bonds and 102 parts. equipped by means of bond sort, sensible crew, bond order, bond measure, molecular dimension, and constitution, the knowledge is usually situated utilizing the Periodic desk. The booklet offers facts for organics, biochemicals, and radicals in addition to clusters, ions, hydrogen- and surface-bonded species, Van der Waals complexes, and halogen-clusters/complexes. It additionally introduces fullyyt new information for inorganics and organometallics and summarizes the heats of formation for atoms, unfastened radicals, and monoatomic ions within the fuel section.
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Extra resources for Comprehensive Handbook of Chemical Bond Energies
Bond order (triple, double, and single) and the bond degree (primary, secondary, or tertiary). The compounds with triple bond and primary BDEs are listed ﬁrst. 4. Saturated or unsaturated compounds. Saturated ones are listed ﬁrst. 5. Molecular size. The BDEs of smaller molecules are arranged ﬁrst. 6. Molecular shape (chain or cyclic). The BDEs of chain molecules are arranged ﬁrst. 7. While substituent(s)-containing, please ﬁrst search the bonds in the parent molecules. For example, the C–H BDEs in substituted toluene are listed under C6H5CH2–H.
2 What is the BDE? 15 K. 1 7366—CHAPTER 1—5/2/2007—12:59—KARTHIA—15357—XML MODEL B – pp. 1–11 2 Comprehensive Handbook of Chemical Bond Energies Therefore, the BDE is also called the bond dissociation enthalpy. Here, species RX represent molecules, radicals, ions, and complexes, as well as clusters. The BDEs are commonly referred to as bond energies, bond strengths, binding energies, or bond disruption energies (enthalpies). The BE or D are other simpliﬁed abbreviation of the BDE in the literature.
We now have collected experimental data on over 19,600 bonds of 102 elements. A new publication that completely compiles all available BDEs will be of beneﬁt to chemists, biochemists, and chemical engineers. 4 Scope of this book The experimental BDEs of many important compounds have been measured many times. A typical example is C–H BDE in methane. 1 kcal/mol. Although we have collected experimental data, it is not necessary to include all of the data in this book because most users are concerned with reliable experimental values only.
Comprehensive Handbook of Chemical Bond Energies by Yu-Ran Luo