By Arthur Adamson (Auth.)
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Extra resources for A Textbook of Physical Chemistry
The Problems section contains more demanding and often longer applications of the same material; and, as the name indicates, Special Topics Problems draw on the Special Topics section of the chapter. Numbers given to one significant figure are to be taken as exact. Problems marked with an asterisk require fairly lengthy computations. EXERCISES 33 EXERCISES 1-1 Calculate the molar volume V and the density of methane gas at STP assuming ideal 3 behavior. Ans. 5 atm pressure. Ans. 158 x l O ^ g c m " .
Use the curves of Figs. 1-8 and 1-9 as a guide. 1-25 Using the Hougen-Watson chart (Fig. 1-10) and the critical constants (Table 1-4) for CO, obtain the value for the second virial coefficient for CO at 25°C. It is suggested that a graphical method be used. 7 1-26 6 -2 3 gas -obeys 1 A certain the van der Waals equation with a = 10 atm cm m o l e and b = 100 cm m o l e . Calculate the volume of four moles of the gas when the pressure is 5 atm and the temperature is 300°C. SPECIAL T O P I C S P R O B L E M S 1-1 Calculate B(T) for N H at 25°C (a) using its van der Waals constants and (b) assuming 3 the hard-sphere model and using only the density of liquid ammonia.
1946). " Van Nostrand-Reinhold, Princeton, New Jersey. HIRSCHFELDER, J. , CURTISS, C. , AND BIRD, R. B . (1964). "Molecular Theory of Gases and Liquids," corrected ed. Wiley, New York. MACDOUGALL, F. H . (1936). / . Amer. Chem. Soc. 5 8 , 2585. WESTON, F. (1950). "An Introduction to Thermodynamics. " Addison-Wesley, Reading, Massachusetts. EXERCISES AND PROBLEMS As noted in the Preface, each section of this type is divided into three parts. The first consists of Exercises, or very straightforward illustrations of the textual material.
A Textbook of Physical Chemistry by Arthur Adamson (Auth.)